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Enhanced proton conductivity in zirconium-rich perovskites via barium diffusion-assisted low-temperature sintering

This study demonstrated the Ba-diffusion-assisted sintering strategy that enables complete densification of BaCe0.4Zr0.4Y0.1Yb0.1O3₋δ (BCZYYb4411) electrolytes at substantially reduced temperatures (1200-1400°C) compared to conventional methods (≥1600°C). By controlling barium carbonate (BaCO3)... Click to show full abstract

This study demonstrated the Ba-diffusion-assisted sintering strategy that enables complete densification of BaCe0.4Zr0.4Y0.1Yb0.1O3₋δ (BCZYYb4411) electrolytes at substantially reduced temperatures (1200-1400°C) compared to conventional methods (≥1600°C). By controlling barium carbonate (BaCO3)...

Keywords: diffusion assisted; enhanced proton; conductivity zirconium; proton conductivity; diffusion; barium

Journal Title: Journal of Materials Chemistry A
Year Published: 2025

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