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Pressure- and temperature-driven transitions and conformational conversions of n-hexyl substituted perylene diimide (PDI-C6) crystals

PDI-C6 remarkably diverts between five polymorps of the same space-group type. Pressure modifies the n-hexyl chains only, while temperature both scissors-like rotates the perylene cores and changes the conformation of… Click to show full abstract

PDI-C6 remarkably diverts between five polymorps of the same space-group type. Pressure modifies the n-hexyl chains only, while temperature both scissors-like rotates the perylene cores and changes the conformation of n-hexyl chains.

Keywords: pressure; pdi; pressure temperature; driven transitions; temperature driven; transitions conformational

Journal Title: Journal of Materials Chemistry C
Year Published: 2025

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