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We herein disclose the first Ni-catalyzed Hiyama coupling of aryl halides with vinylsilanes. This protocol uses cheap, nontoxic, and stable vinyltrimethoxysilane as the vinyl donor, proceeds under mild and ligand-free… Click to show full abstract
We herein disclose the first Ni-catalyzed Hiyama coupling of aryl halides with vinylsilanes. This protocol uses cheap, nontoxic, and stable vinyltrimethoxysilane as the vinyl donor, proceeds under mild and ligand-free conditions, furnishing a diverse variety of styrene derivatives in high yields with excellent functional group compatibility.
Keywords:
nickel catalyzed;
ligand free;
coupling aryl;
catalyzed ligand;
hiyama coupling
Journal Title: Synlett
Year Published: 2021
Link to full text (if available)
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Journal Title: Synlett
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!