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Synthesis of Diporphyrins by Oxidative Coupling with Pd(TFA)2-Cu(OTf)2 under Ball-Milling Conditions

A sustainable synthetic method for the synthesis of diporphyrins under ball-milling conditions is reported. The meso-meso linked diporphyrins are efficiently accessed by direct oxidative homo-coupling of porphyrins with Pd(TFA)2 as… Click to show full abstract

A sustainable synthetic method for the synthesis of diporphyrins under ball-milling conditions is reported. The meso-meso linked diporphyrins are efficiently accessed by direct oxidative homo-coupling of porphyrins with Pd(TFA)2 as the catalyst and Cu(OTf)2 as the oxidant.

Keywords: diporphyrins oxidative; oxidative coupling; synthesis diporphyrins; ball milling; milling conditions

Journal Title: Synthesis
Year Published: 2021

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