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Trialkylsilyllithium species have turned out to be facilely generated by treating hexaalkyldisilanes with methyllithium in the presence of tris(N,N-tetramethylene)phosphoric triamide (TPPA) as an activator, which can be trapped by boron… Click to show full abstract
Trialkylsilyllithium species have turned out to be facilely generated by treating hexaalkyldisilanes with methyllithium in the presence of tris(N,N-tetramethylene)phosphoric triamide (TPPA) as an activator, which can be trapped by boron electrophiles to afford silylboronic esters including long-awaited Me3Si–B(pin).
Keywords:
trialkylsilyllithium reagents;
silylboronic esters;
trialkylsilyllithium;
free generation;
generation trialkylsilyllithium;
hmpa free
Journal Title: Synthesis
Year Published: 2021
Link to full text (if available)
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Journal Title: Synthesis
Year Published: 2021
Link to full text (if available)
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recommendations!