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A Pd-catalyzed asymmetric phosphination of α, β-unsaturated sulfonyl fluorides was developed, and a series of tertiary phosphorus compounds were obtained in excellent yields and enantioselectivities (up to 99% ee). The… Click to show full abstract
A Pd-catalyzed asymmetric phosphination of α, β-unsaturated sulfonyl fluorides was developed, and a series of tertiary phosphorus compounds were obtained in excellent yields and enantioselectivities (up to 99% ee). The chiral adduct can be further converted into chiral phosphine sulfonic acid as the ligand for the arene Ru metal complex.
Keywords:
unsaturated sulfonyl;
palladium catalyzed;
asymmetric addition;
catalyzed asymmetric;
sulfonyl fluorides;
addition diarylphosphines
Journal Title: Synthesis
Year Published: 2023
Link to full text (if available)
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Journal Title: Synthesis
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!