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Hierarchical Supramolecular Nanostructures of Cyclic Hydrogen-Bonding Catemers in Dibenzo[ a , c ]phenazinecarboxylic Acid Discotic Liquid Crystals

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The hydrogen bonding motif of Dibenzo[a,c]phenazine carboxylic acid can be enforced to form hierarchical cyclic hydrogen bonded trimers for creating 3D Colh assembly at the mesophase, as demonstrated by XRD… Click to show full abstract

The hydrogen bonding motif of Dibenzo[a,c]phenazine carboxylic acid can be enforced to form hierarchical cyclic hydrogen bonded trimers for creating 3D Colh assembly at the mesophase, as demonstrated by XRD diffractions. Scanning tunneling microscopy has been used to characterized the formation of the cyclic trimer. Atomic force microscopy revealed the formation of nanopillars on hydrophilized silica surface upon annealing from isotropic to room temperature.

Keywords: cyclic hydrogen; hydrogen bonding; hierarchical supramolecular; microscopy; hydrogen; supramolecular nanostructures

Journal Title: Synthesis
Year Published: 2023

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