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The use of pyridine as the sole ligand for the reductive vinylation of unactivated secondary alkyl halides under Ni-catalyzed conditions has been developed. Both alkyl- and aryl-substituted vinyl bromides are… Click to show full abstract
The use of pyridine as the sole ligand for the reductive vinylation of unactivated secondary alkyl halides under Ni-catalyzed conditions has been developed. Both alkyl- and aryl-substituted vinyl bromides are suitable, in which alkyl-decorated α-alkenyl bromides resulted in the α-products in good results.
Keywords:
alkyl halides;
reductive cross;
vinyl bromides;
catalyzed reductive;
nickel catalyzed;
cross coupling
Journal Title: Synthesis
Year Published: 2017
Link to full text (if available)
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Journal Title: Synthesis
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!