(HMe2SiCH2)2 has been utilized as a useful reagent for B(C6F5)3-catalyzed reduction–lactonization of keto acids to synthesize γ- and δ-lactones. The process led concisely to (–)-cis-whisky and (–)-cis-cognac lactones in respective… Click to show full abstract
(HMe2SiCH2)2 has been utilized as a useful reagent for B(C6F5)3-catalyzed reduction–lactonization of keto acids to synthesize γ- and δ-lactones. The process led concisely to (–)-cis-whisky and (–)-cis-cognac lactones in respective overall yields of 32% and 36%.
Keywords:
reagent c6f5;
reduction lactonization;
c6f5 catalyzed;
lactonization keto;
catalyzed reduction;
useful reagent
Journal Title: Synlett
Year Published: 2017
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Journal Title: Synlett
Year Published: 2017
Link to full text (if available)
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recommendations!