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Mild and Efficient Vicinal Dibromination of Olefins Mediated by Aqueous Ammonium Fluoride

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A mild and efficient vicinal dibromination of olefins has been developed by using saturated aqueous ammonium fluoride solution as the promoter. Inexpensive and commercially available N -bromosuccinimide (NBS) was used… Click to show full abstract

A mild and efficient vicinal dibromination of olefins has been developed by using saturated aqueous ammonium fluoride solution as the promoter. Inexpensive and commercially available N -bromosuccinimide (NBS) was used as the brominating reagent. The corresponding vicinal dibromoalkanes could be obtained in good to excellent yields.

Keywords: ammonium fluoride; vicinal dibromination; aqueous ammonium; dibromination olefins; mild efficient; efficient vicinal

Journal Title: Synlett
Year Published: 2017

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