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A Pd(OAc) 2 -catalyzed desulfinative cross-coupling of ( Z )-β-halostyrenes with sodium sulfinates in the presence of PPh 3 and Na 2 CO 3 at reflux in good yields is… Click to show full abstract
A Pd(OAc) 2 -catalyzed desulfinative cross-coupling of ( Z )-β-halostyrenes with sodium sulfinates in the presence of PPh 3 and Na 2 CO 3 at reflux in good yields is reported. The stereocontrolled cross-coupling process provides a series of sulfonylmethyl ( Z )-stilbenes. A synthesis of tamoxifen was studied.
Keywords:
catalyzed desulfinative;
oac catalyzed;
desulfinative cross;
cross;
synthesis;
cross coupling
Journal Title: Synthesis
Year Published: 2017
Link to full text (if available)
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Journal Title: Synthesis
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!