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Iron-Catalyzed Carbenoid Insertion into C(sp3)–H Bonds

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An iron-catalyzed carbenoid insertion into C–H bonds of alkanes was developed with high activity (turnover numbers up to 690 in a gram-scale experiment) and chemoselectivity. This non-heme iron-catalyzed C(sp3)–H insertion… Click to show full abstract

An iron-catalyzed carbenoid insertion into C–H bonds of alkanes was developed with high activity (turnover numbers up to 690 in a gram-scale experiment) and chemoselectivity. This non-heme iron-catalyzed C(sp3)–H insertion reaction provides an efficient strategy for C–H functionalization.

Keywords: insertion; iron catalyzed; catalyzed carbenoid; sp3 bonds; insertion sp3; carbenoid insertion

Journal Title: Synlett
Year Published: 2017

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