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Nickel-Catalyzed Cross-Coupling of Functionalized Organo­manganese Reagents with Aryl and Heteroaryl Halides Promoted by 4-Fluorostyrene

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A catalytic system consisting of Ni(acac)2 (5 mol%) and 4-fluorostyrene (20 mol%) allows a convenient cross-coupling of functionalized organomanganese reagents with a variety of aryl and heteroaryl halides leading to… Click to show full abstract

A catalytic system consisting of Ni(acac)2 (5 mol%) and 4-fluorostyrene (20 mol%) allows a convenient cross-coupling of functionalized organomanganese reagents with a variety of aryl and heteroaryl halides leading to polyfunctionalized diaryl- and arylheteroarylmethane derivatives.

Keywords: coupling functionalized; aryl heteroaryl; heteroaryl halides; nickel catalyzed; cross coupling

Journal Title: Synthesis
Year Published: 2017

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