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Highly Active Manganese-Mediated Acylation of Alcohols with Acid Chlorides or Anhydrides

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To explore further the practical uses of highly active manganese (Mn*), a variety of alcohols were treated with Mn*, and the resulting complexes were coupled with acid chlorides and/or acetic… Click to show full abstract

To explore further the practical uses of highly active manganese (Mn*), a variety of alcohols were treated with Mn*, and the resulting complexes were coupled with acid chlorides and/or acetic anhydride in the absence of any extra catalyst. The subsequent reactions took place smoothly under mild conditions, providing the corresponding O-acylation products in good to excellent isolated yields.

Keywords: active manganese; manganese mediated; highly active; mediated acylation; acid chlorides

Journal Title: Synlett
Year Published: 2017

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