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Copper-Catalyzed Production of Diaryl Sulfides Using Aryl Iodides and a Disilathiane

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A disilathiane was found to be a novel S1 source for the copper-catalyzed synthesis of diaryl sulfides using aryl iodides. The reaction of iodoarenes and hexamethyldisilathiane, (Me 3 Si) 2… Click to show full abstract

A disilathiane was found to be a novel S1 source for the copper-catalyzed synthesis of diaryl sulfides using aryl iodides. The reaction of iodoarenes and hexamethyldisilathiane, (Me 3 Si) 2 S, in the presence of a catalytic amount of CuI/1,10-phenanthroline provided various types of diaryl sulfides in good yields.

Keywords: diaryl sulfides; using aryl; aryl iodides; sulfides using; copper catalyzed

Journal Title: Synlett
Year Published: 2017

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