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An effective method for the P-alkylation of N-arylphosphinecarboxamides was demonstrated. Primary N-arylphosphinecarboxamides without additional protection underwent P-monoalkylation with various alkyl halides in the presence of cesium carbonate as a promoter.… Click to show full abstract
An effective method for the P-alkylation of N-arylphosphinecarboxamides was demonstrated. Primary N-arylphosphinecarboxamides without additional protection underwent P-monoalkylation with various alkyl halides in the presence of cesium carbonate as a promoter. The reactivity of phosphinecarboxamides was also explored.
Keywords:
cesium carbonate;
carbonate promoted;
alkylation phosphinecarboxamides;
promoted alkylation;
alkylation
Journal Title: Synlett
Year Published: 2018
Link to full text (if available)
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Journal Title: Synlett
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!