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The asymmetric transfer hydrogenation of ketones using isopropyl alcohol (IPA) as hydrogen donor in the presence of novel manganese catalysts is explored. The selective and active systems are easily generated… Click to show full abstract
The asymmetric transfer hydrogenation of ketones using isopropyl alcohol (IPA) as hydrogen donor in the presence of novel manganese catalysts is explored. The selective and active systems are easily generated in situ from [MnBr(CO)5] and inexpensive C 2-symmeric bisoxalamide ligands. Under the optimized reaction conditions, the Mn-derived catalyst gave higher enantioselectivity compared with the related ruthenium catalyst.
Keywords:
ketones using;
transfer hydrogenation;
hydrogenation ketones;
asymmetric transfer
Journal Title: Synlett
Year Published: 2019
Link to full text (if available)
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Journal Title: Synlett
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!