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Base-Metal-Catalyzed Olefin Isomerization Reactions

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The catalytic olefin isomerization reaction is a highly efficient and atom-economic transformation in organic synthesis that has attracted tremendous attention both in academia and industry. Recently, the development of Earth-abundant… Click to show full abstract

The catalytic olefin isomerization reaction is a highly efficient and atom-economic transformation in organic synthesis that has attracted tremendous attention both in academia and industry. Recently, the development of Earth-abundant metal catalysts has received growing interest owing to their wide availability, sustainability, and ­environmentally benign nature, as well as the unique properties of non-precious metals. This review provides an overview of a broad range of base-metal-catalyzed olefin isomerization reactions categorized ­according to their different reaction mechanisms.1 Introduction2 Base-Metal-Catalyzed Olefin Isomerization Reactions3 Base-Metal-Catalyzed Cycloisomerization Reactions4 Conclusion

Keywords: base metal; metal; metal catalyzed; olefin isomerization; catalyzed olefin

Journal Title: Synthesis
Year Published: 2019

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