Photo by miracleday from unsplash
A nickel catalyst for the allylboration of aldehydes is reported, facilitating the preparation of homoallylic alcohols in high diastereoselectivity. The observed diastereoselectivities and NMR experiments suggest that allylation occurs through… Click to show full abstract
A nickel catalyst for the allylboration of aldehydes is reported, facilitating the preparation of homoallylic alcohols in high diastereoselectivity. The observed diastereoselectivities and NMR experiments suggest that allylation occurs through a well-defined six-membered transition state, with nickel acting as a Lewis acid.
Keywords:
allylboration;
nickel catalysed;
catalysed allylboration;
allylboration aldehydes
Journal Title: Synthesis
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Synthesis
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!