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A practical protocol for efficient synthesis of both PAMPO enantiomers as well as related functionalised P-stereogenic phosphine oxides in 1–3 steps from effectively resolved (S P)- l -menthyl o-anisyl-(phenyl)phosphinylacetate has… Click to show full abstract
A practical protocol for efficient synthesis of both PAMPO enantiomers as well as related functionalised P-stereogenic phosphine oxides in 1–3 steps from effectively resolved (S P)- l -menthyl o-anisyl-(phenyl)phosphinylacetate has been developed. Examples of non-stereoselective quaternisation of a tertiary phosphine by alkyl halides have been revealed.
Keywords:
synthesis pampo;
enantiodivergent synthesis;
quaternisation;
synthesis;
pampo enantiomers
Journal Title: Synthesis
Year Published: 2019
Link to full text (if available)
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Journal Title: Synthesis
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!