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An oxidative annulation for the synthesis of 2,4-diarylquinolines from o-allylanilines is disclosed that uses recyclable reagent Chloranil as the oxidant. The corresponding products are obtained in moderate to excellent yields.… Click to show full abstract
An oxidative annulation for the synthesis of 2,4-diarylquinolines from o-allylanilines is disclosed that uses recyclable reagent Chloranil as the oxidant. The corresponding products are obtained in moderate to excellent yields. Furthermore, a one-pot access to 2,4-diarylquinolines from easily available anilines and 1,3-diarylpropenes is described as a highly atom-efficient protocol that involves oxidative coupling, rearrangement, and oxidative annulation.
Keywords:
annulation;
oxidative annulation;
chloranil;
one pot;
synthesis
Journal Title: Synthesis
Year Published: 2020
Link to full text (if available)
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Journal Title: Synthesis
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!