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An asymmetric arylation of H-phosphinates with aromatic iodo or bromo compounds, catalyzed by cheap and easily available nickel(II) salts, provides access to P-stereogenic phosphinates. This method features mild reaction conditions… Click to show full abstract
An asymmetric arylation of H-phosphinates with aromatic iodo or bromo compounds, catalyzed by cheap and easily available nickel(II) salts, provides access to P-stereogenic phosphinates. This method features mild reaction conditions and a good functional-group compatibility that includes aniline and phenol derivatives.
Keywords:
catalyzed asymmetric;
nickel catalyzed;
asymmetric arylation;
arylation phosphinates
Journal Title: Synlett
Year Published: 2023
Link to full text (if available)
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Journal Title: Synlett
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!