Magnetic Yttrium Iron Garnet (YIG) nanoparticles (NPs) were prepared by sol–gel (SG) and solid-state (SS) reaction methods to elucidate the nanoscale size on the magnetic behavior of NPs. It is… Click to show full abstract
Magnetic Yttrium Iron Garnet (YIG) nanoparticles (NPs) were prepared by sol–gel (SG) and solid-state (SS) reaction methods to elucidate the nanoscale size on the magnetic behavior of NPs. It is found that YIG prepared by these two methods are different in many ways. The average NP sizes prepared by SG and SS methods were calculated by Scherrer formula from XRD data. SEM images show the change in grain size for both types of NPs. The sintering temperature required to form pure garnet phase is 750°C for SG and 1000°C for SS NPs. The saturation magnetizations (Ms) were 1070 Oe for SG and 1125 Oe for SS NPs, respectively. The coercivity (Hc) of SS NPs are twice larger than SG NPs. This is due to the larger crystal sizes of the SS NPs, hence more crystal boundaries. Dynamic properties were studied by ferromagnetic resonance (FMR) technique in field-sweep and frequency-sweep mode at different fixed frequencies and at different fixed magnetic fields, respectively. Resonance field (Hr) observed to increase linear...
               
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