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Electromechanical properties of electrostrictive CeO2:Gd membranes: Effects of frequency and temperature

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Doped ceria is known for decades as an excellent ionic conductor used ubiquitously in fuel cells and other devices. Recent discovery of a giant electrostriction effect has brought world-wide interest… Click to show full abstract

Doped ceria is known for decades as an excellent ionic conductor used ubiquitously in fuel cells and other devices. Recent discovery of a giant electrostriction effect has brought world-wide interest to this class of materials for actuation applications in micromechanical systems. From this aspect, the electromechanical response has to be studied as a function of external parameters, such as frequency, temperature, and electrode material. In this work, we fabricated circular membranes based on Gd-doped ceria (CGO) with Ti electrodes and studied their electromechanical response using a sensitive interferometric technique. The self-supported membranes are flat at room temperature and reversibly buckle upon heating, indicating that the membranes are under in-plane tensile strain. We have found that the electromechanical response is strongly frequency dependent. Significant hysteresis is observed in the displacement-vs.-voltage curves, which is deleterious for micromechanical applications but can be eliminate...

Keywords: frequency temperature; ceo2 membranes; properties electrostrictive; electrostrictive ceo2; electromechanical properties; electromechanical response

Journal Title: Applied Physics Letters
Year Published: 2017

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