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Application of nonlinear rheology to assess the effect of secondary nanofiller on network structure of hybrid polymer nanocomposites

Carbon nanotube (CNT)/polymer nanocomposites exhibit excellent electrical properties by forming a percolated network. Adding a secondary filler can significantly affect the CNTs’ network, resulting in changing the electrical properties. In… Click to show full abstract

Carbon nanotube (CNT)/polymer nanocomposites exhibit excellent electrical properties by forming a percolated network. Adding a secondary filler can significantly affect the CNTs’ network, resulting in changing the electrical properties. In this work, we investigated the effect of adding manganese dioxide nanowires (MnO2NWs) as a secondary nanofiller on the CNTs’ network structure inside a poly(vinylidene fluoride) (PVDF) matrix. Incorporating MnO2NWs to PVDF/CNT samples produced a better state of dispersion of CNTs, as corroborated by light microscopy and transmission electron microscopy. The steady shear and oscillatory shear flows were employed to obtain a better insight into the nanofiller structure and viscoelastic behavior of the nanocomposites. The transient response under steady shear flow revealed that the stress overshoot of hybrid nanocomposites (two-fillers), PVDF/CNT/MnO2NWs, increased dramatically in comparison to binary nanocomposites (single-filler), PVDF/CNT and PVDF/MnO2NWs. This can be a...

Keywords: polymer nanocomposites; network; microscopy; rheology; nanofiller; structure

Journal Title: Physics of Fluids
Year Published: 2018

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