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Growth of large diameter pure phase wurtzite GaP nanowires by a two-step axial-radial growth approach

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Direct bandgap wurzite (WZ) GaP nanowires (NWs) are projected as a non-nitride solution to the green gap in the LED technology. Here, we report on the growth of 5 μm long… Click to show full abstract

Direct bandgap wurzite (WZ) GaP nanowires (NWs) are projected as a non-nitride solution to the green gap in the LED technology. Here, we report on the growth of 5 μm long pure WZ GaP NWs having a diameter of 200 nm by a two-step core-clad approach. Transmission electron microscopy indicates the absence of any planar defects in the NWs. The low temperature photoluminescence (PL) spectrum of the NWs differs markedly from their non-pure counterparts, previously reported. From the PL spectrum, the bandgap of wurtzite GaP at 10 K is 2.13 eV. This value differs from previously reported values.Direct bandgap wurzite (WZ) GaP nanowires (NWs) are projected as a non-nitride solution to the green gap in the LED technology. Here, we report on the growth of 5 μm long pure WZ GaP NWs having a diameter of 200 nm by a two-step core-clad approach. Transmission electron microscopy indicates the absence of any planar defects in the NWs. The low temperature photoluminescence (PL) spectrum of the NWs differs markedly from their non-pure counterparts, previously reported. From the PL spectrum, the bandgap of wurtzite GaP at 10 K is 2.13 eV. This value differs from previously reported values.

Keywords: gap; pure; microscopy; two step; gap nanowires; growth

Journal Title: Applied Physics Letters
Year Published: 2018

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