LAUSR

The fullerene C60, C70, and C84 molecules, that are composed of ∼99% naturally abundant 12C having spinless nuclei, are considered to have miniature hyperfine interaction and also weak intrinsic spin-orbit coupling (SOC) due to the light carbon atoms. However, it has been theoretically predicted that the curvature of the fullerene molecules may increase the SOC due to the induced hybridization of the π and σ electrons on the carbon atoms that reside on the fullerene molecule surface. In this work, we have measured the spin diffusion length in films of C60, C70, and C84 in NiFe/fullerene/Pt trilayer devices, where pure spin current is injected into the fullerene film at the NiFe/fullerene interface via spin pumping induced by microwave absorption at ferromagnet resonance conditions, and subsequently detected at the fullerene/Pt interface as electrical current via the inverse spin-Hall effect. The obtained spin diffusion lengths in the fullerene films are of the order of 10 nm and increase from C60 to C84 in which the fullerene molecule’s curvature decreases; this finding validates the existence of curvature-induced SOC in the fullerenes. Our results deepen the understanding of spin transport in fullerene films and may benefit the design of molecular spintronic devices.The fullerene C60, C70, and C84 molecules, that are composed of ∼99% naturally abundant 12C having spinless nuclei, are considered to have miniature hyperfine interaction and also weak intrinsic spin-orbit coupling (SOC) due to the light carbon atoms. However, it has been theoretically predicted that the curvature of the fullerene molecules may increase the SOC due to the induced hybridization of the π and σ electrons on the carbon atoms that reside on the fullerene molecule surface. In this work, we have measured the spin diffusion length in films of C60, C70, and C84 in NiFe/fullerene/Pt trilayer devices, where pure spin current is injected into the fullerene film at the NiFe/fullerene interface via spin pumping induced by microwave absorption at ferromagnet resonance conditions, and subsequently detected at the fullerene/Pt interface as electrical current via the inverse spin-Hall effect. The obtained spin diffusion lengths in the fullerene films are of the order of 10 nm and increase from C60 to C84...