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Optical and electrical characteristics of carbonized film prepared from coal tar pitch under a high magnetic field of 10 T

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Carbon microcrystallites can become oriented in the carbonization process of coal tar pitch, which occurs with the characteristic where a mesophase is obtained, by using a magnetic field. An oriented… Click to show full abstract

Carbon microcrystallites can become oriented in the carbonization process of coal tar pitch, which occurs with the characteristic where a mesophase is obtained, by using a magnetic field. An oriented film that has the ability to transmit visible light from 450 to 800 nm can be obtained by sandwiching an appropriate amount of coal pitch between two glass plates and heating in an inert atmosphere at 793 K under a magnetic field. This film can be used to obtain the same linearly polarized light as a commercially available polarizing element. The degree of orientation of the film prepared in a magnetic field of 3 T is not sufficient to use as a polarizer, but a magnetic field of 6 T is able to sufficiently suppress the passage of crossed polarized light. The electrical conductivity of the carbon film prepared at 793 K is improved by 10 times by the application of a magnetic field of 10 T. The electrical conductivity is sensitive to the magnetic field, and there is a possibility that it can be further improved by applying 10 T or more. Coal tar pitch is the residue after obtaining coke from coal, and the optical and electrical advantage of a material prepared in the magnetic field derived from such natural products is clarified.Carbon microcrystallites can become oriented in the carbonization process of coal tar pitch, which occurs with the characteristic where a mesophase is obtained, by using a magnetic field. An oriented film that has the ability to transmit visible light from 450 to 800 nm can be obtained by sandwiching an appropriate amount of coal pitch between two glass plates and heating in an inert atmosphere at 793 K under a magnetic field. This film can be used to obtain the same linearly polarized light as a commercially available polarizing element. The degree of orientation of the film prepared in a magnetic field of 3 T is not sufficient to use as a polarizer, but a magnetic field of 6 T is able to sufficiently suppress the passage of crossed polarized light. The electrical conductivity of the carbon film prepared at 793 K is improved by 10 times by the application of a magnetic field of 10 T. The electrical conductivity is sensitive to the magnetic field, and there is a possibility that it can be further improved...

Keywords: pitch; field; film prepared; magnetic field; coal

Journal Title: Journal of Applied Physics
Year Published: 2019

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