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A low band gap diketopyrrolopyrrole-based polymer: Synthesis, thermal and optical properties

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ABSTRACT In this work, P-DPP, which was a low band gap polymer based on diketopyrrolopyrrole (DPP) and cyclopentadithiophene (CPDT), was synthesized through palladium-catalyzed Stille coupling reaction. Due to the strong… Click to show full abstract

ABSTRACT In this work, P-DPP, which was a low band gap polymer based on diketopyrrolopyrrole (DPP) and cyclopentadithiophene (CPDT), was synthesized through palladium-catalyzed Stille coupling reaction. Due to the strong electron-donating property of CPDT and strong withdrawing property of DPP, P-DPP exhibited narrow band gap of 1.29 eV. The thermal and optical properties of P-DPP had been carefully investigated.

Keywords: gap; band gap; optical properties; thermal optical; low band; gap diketopyrrolopyrrole

Journal Title: Ferroelectrics
Year Published: 2018

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