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Electrospun copper oxide nanofibers and catalysis for combustion of ammonium perchlorate

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Abstract Copper oxide (CuO) nanofibers were successfully prepared by electrospinning and subsequent heat treatment. The chemical composition and morphology of the fibers were characterized by SEM, XRD and EDS. Beaded… Click to show full abstract

Abstract Copper oxide (CuO) nanofibers were successfully prepared by electrospinning and subsequent heat treatment. The chemical composition and morphology of the fibers were characterized by SEM, XRD and EDS. Beaded nanofibers with 100nm in diameter were prepared by simple electrospinning and calcining. The catalytic effect of CuO nanofibers on the combustion of ammonium perchlorate (AP) was investigated by TG and DTA. The results showed that the decomposition temperature of AP shifted by 101.9 °C to the low temperature and the catalytic efficiency was very high. This is mainly attributed to the higher surface to volume ratio of beaded copper oxide nanofibers compared with smooth nanofibers and spherical nanoparticles. The results suggest that the electrospinning of CuO nanofibers is a promising one-dimensional nanometer material in the field of propellant catalysis.

Keywords: ammonium perchlorate; combustion ammonium; oxide nanofibers; copper; copper oxide

Journal Title: Ferroelectrics
Year Published: 2019

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