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ABSTRACT We report measurements of the vapour–liquid coexistence densities and surface tension of fully flexible Lennard–Jones chain molecules ranging in length from 4 to 60 beads. We demonstrate that the… Click to show full abstract
ABSTRACT We report measurements of the vapour–liquid coexistence densities and surface tension of fully flexible Lennard–Jones chain molecules ranging in length from 4 to 60 beads. We demonstrate that the surface tension for all chain lengths collapses to a single master curve when plotted according to the universal parachor correlation. We find a universal parachor exponent 3.79 ± 0.05 for conditions close to the critical point, with a deviation observed for the longest chains far below the critical point.
Keywords:
fully flexible;
surface tension;
tension fully;
tension;
vapour liquid;
flexible lennard
Journal Title: Molecular Physics
Year Published: 2017
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Journal Title: Molecular Physics
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!