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ABSTRACT An efficient [Cu]-catalyzed homocoupling of 1,1-dibromoalk-1-enes is described for the synthesis of symmetrical 1,3-diyines. The method showed good substrate scope and amenable to aryl and heteroaryl systems. Significantly, the… Click to show full abstract
ABSTRACT An efficient [Cu]-catalyzed homocoupling of 1,1-dibromoalk-1-enes is described for the synthesis of symmetrical 1,3-diyines. The method showed good substrate scope and amenable to aryl and heteroaryl systems. Significantly, the strategy was also successfully applied to the sequential one-pot synthesis of triazoles. GRAPHICAL ABSTRACT
Keywords:
coupling dibromoalkenes;
symmetrical diynes;
direct coupling;
dibromoalkenes synthesis;
synthesis symmetrical;
catalyzed direct
Journal Title: Synthetic Communications
Year Published: 2017
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Journal Title: Synthetic Communications
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!