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Dichlorination of olefins with diphenyl sulfoxide/oxalyl chloride

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Abstract The combination of diphenyl sulfoxide and oxalyl chloride was used to accomplish the dichlorination of olefins, in which chlorodiphenylsulfonium salt generated in situ was proposed to be the real… Click to show full abstract

Abstract The combination of diphenyl sulfoxide and oxalyl chloride was used to accomplish the dichlorination of olefins, in which chlorodiphenylsulfonium salt generated in situ was proposed to be the real active species as a chloronium ion source. Graphical Abstract

Keywords: oxalyl chloride; sulfoxide oxalyl; dichlorination olefins; diphenyl sulfoxide

Journal Title: Synthetic Communications
Year Published: 2020

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