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Abstract Enephosphorylamides were herein successfully prepared from phosphorylamides and substituted alkenes. The dehydrogenative transformation took place in the presence of a combination of a palladium diacetate and nickel dichloride. The… Click to show full abstract
Abstract Enephosphorylamides were herein successfully prepared from phosphorylamides and substituted alkenes. The dehydrogenative transformation took place in the presence of a combination of a palladium diacetate and nickel dichloride. The transition metal-catalyzed methodology enjoyed high efficiency and broad substrate scope. Moreover, a plausible mechanism was proposed for the oxidative C–N cross coupling protocol. Graphical Abstract
Keywords:
palladium nickel;
nickel mediated;
mediated cross;
coupling reaction;
cross;
cross coupling
Journal Title: Synthetic Communications
Year Published: 2020
Link to full text (if available)
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Journal Title: Synthetic Communications
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!