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Synthesis, characterization, and catalytic activity of a water soluble copper(II) and nickel(II) heterobimetallic complex [CuNi(μ-OH)(μ-OH2)(μ-OAc)(bpy)2](ClO4)2 in aqueous medium in the absence of a base and co-catalyst

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Abstract A copper(II)–nickel(II)-based catalyst system has been synthesized and characterized by elemental analysis, molar conductance, mass spectra, magnetic moment, EPR, UV-Vis, IR spectroscopy, and cyclic voltammetry. The structure of the… Click to show full abstract

Abstract A copper(II)–nickel(II)-based catalyst system has been synthesized and characterized by elemental analysis, molar conductance, mass spectra, magnetic moment, EPR, UV-Vis, IR spectroscopy, and cyclic voltammetry. The structure of the complex was established by X-ray crystallography. The complex is an efficient catalyst, which oxidizes primary and secondary alcohols to the corresponding aldehydes and ketones at 70 °C employing 15% H2O2 as the oxidant in the absence of a base and co-catalyst.

Keywords: copper nickel; catalyst; absence base; base catalyst

Journal Title: Journal of Coordination Chemistry
Year Published: 2017

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