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Abstract A metal-coordination-driven self-assembly using the predesigned building block has been developed. Herein, the catalytic active NHC–Cu(I) units were introduced into the terpyridine metal coordination polymers. The self-assembled architecture, as… Click to show full abstract
Abstract A metal-coordination-driven self-assembly using the predesigned building block has been developed. Herein, the catalytic active NHC–Cu(I) units were introduced into the terpyridine metal coordination polymers. The self-assembled architecture, as a heterogeneous catalyst, was successfully used to catalyze the A3-coupling reaction of aldehyde, alkyne, and amine and Huisgen 1,3-dipolar cycloaddition reaction of azide and alkyne in high yields.
Keywords:
complex utilizing;
carbene complex;
construction polymeric;
polymeric heterocyclic;
catalyst;
heterocyclic carbene
Journal Title: Journal of Coordination Chemistry
Year Published: 2018
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Journal Title: Journal of Coordination Chemistry
Year Published: 2018
Link to full text (if available)
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recommendations!