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Abstract Supramolecular hybrid (2-ClPy)2{[TeBr6](Br2)} (1) was prepared by the reaction of TeO2, Br2 and 2-chloropyridinium in HBr. In the structure, mononuclear [TeBr6]2− units are connected by {Br2} linkers into 1D… Click to show full abstract
Abstract Supramolecular hybrid (2-ClPy)2{[TeBr6](Br2)} (1) was prepared by the reaction of TeO2, Br2 and 2-chloropyridinium in HBr. In the structure, mononuclear [TeBr6]2− units are connected by {Br2} linkers into 1D zigzag-shaped infinite chains. Energies of halogen bonding were estimated by theoretical methods (1.3–3.3 kcal/mol). Graphical Abstract
Keywords:
br2;
assisted formation;
halogen bonding;
tebr6 br2;
bonding assisted
Journal Title: Journal of Coordination Chemistry
Year Published: 2019
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Journal Title: Journal of Coordination Chemistry
Year Published: 2019
Link to full text (if available)
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recommendations!