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Highly Selective Polymerization of Rac-Lactide Initiated by Salen Aluminum Complex Bearing an Adamantane Derivative

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Abstract Using adamantane-1,3-diamine and 3,5-di-tert-butylsalicylic aldehyde as raw materials, the generated salen aluminum complex was characterized by 1H, 13C NMR spectroscopy and elemental analysis. After isopropyl alcohol activation treatment, the… Click to show full abstract

Abstract Using adamantane-1,3-diamine and 3,5-di-tert-butylsalicylic aldehyde as raw materials, the generated salen aluminum complex was characterized by 1H, 13C NMR spectroscopy and elemental analysis. After isopropyl alcohol activation treatment, the complex has good activity (70.3-95.6%), which can provide poly(D,L-lactide) with a P m of 0.87 for rac-lactide. Graphical Abstract

Keywords: salen aluminum; rac lactide; highly selective; aluminum complex

Journal Title: Journal of Coordination Chemistry
Year Published: 2021

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