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Thermal and dielectric properties of ferroelectric lead germanate single crystals doped with chromium ions (Pb5Ge3O11:Cr3+)

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ABSTRACT Single crystals of Pb5Ge3O11 (PGO), pure and doped with Cr3+ ions, were grown by means of Czochralski and Kyropoulos method, respectively. Structural, microstructural, thermodynamic and dielectric properties were investigated… Click to show full abstract

ABSTRACT Single crystals of Pb5Ge3O11 (PGO), pure and doped with Cr3+ ions, were grown by means of Czochralski and Kyropoulos method, respectively. Structural, microstructural, thermodynamic and dielectric properties were investigated in terms of Cr3+-doping. The temperature dependences of molar heat capacity in the range 120–700 K at constant pressure (cp) for PGO and PGO:Cr3+ (0.2%) crystals were shown. Wide λ-shape anomalies correspond to the second-order phase transitions from ferroelectric to the paraelectric phase taking place at 453 K and 431 K for PGO and PGO:Cr3+ (0.2%), respectively. The temperature dependences of cp for investigated crystals were approximated by the Einstein function and near the Curie temperature the cp reaches the classical Dulong-Petit limited value ∼475 J·mol−1·K−1. Temperature dependences of dielectric permittivity measured along and perpendicular to the ferroelectric axis in the temperature range 300–550 K are investigated. These studies revealed anisotropic behavior of PGO and PGO:Cr3+ (0.2%) crystals.

Keywords: cr3; dielectric properties; single crystals; pgo; temperature dependences

Journal Title: Phase Transitions
Year Published: 2018

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