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Structural and dielectric anomaly in Na1−XKxNbO3, at x = 0.315

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ABSTRACT Structural and dielectric properties of sodium-potassium niobate (Na1−x KxNbO3) (0.250 ≤ x ≤ 0.350) ceramics, prepared by the solid-state reaction method were investigated. Observed dielectric properties show a strong compositional dependence, at all… Click to show full abstract

ABSTRACT Structural and dielectric properties of sodium-potassium niobate (Na1−x KxNbO3) (0.250 ≤ x ≤ 0.350) ceramics, prepared by the solid-state reaction method were investigated. Observed dielectric properties show a strong compositional dependence, at all the measured temperatures (from room temperature to 150°C) and frequencies (from 1 to 1000 kHz). In the prepared compositions, the lowest values of dielectric permittivity, loss tangent and electrical conductivity were found, and an anomaly in the shifting pattern of X-ray diffraction (XRD) peaks and change in the slope of a/c vs. x plot were observed at x = 0.315. The observed structural and dielectric anomaly gives a morphotropic phase boundary-like indication, in Na1−xKxNbO3 system, at x = 0.315.

Keywords: dielectric anomaly; na1 xkxnbo3; structural dielectric; anomaly na1

Journal Title: Phase Transitions
Year Published: 2019

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