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Stripping of Fe(III) from Aliquat 336 by NaH2PO4: implication for rare-earth elements recovery from red mud

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ABSTRACT A new approach was developed using NaH2PO4 as the stripping agent for Fe stripping from Fe-loaded Aliquat 336 during rare-earth elements recovery from red mud leachate. Owing to the… Click to show full abstract

ABSTRACT A new approach was developed using NaH2PO4 as the stripping agent for Fe stripping from Fe-loaded Aliquat 336 during rare-earth elements recovery from red mud leachate. Owing to the strong coordination between Fe3+ and H2PO4 ‒, Fe mainly exists as FeH2PO4 2+ at [H2PO4 ‒] higher than 0.5 M, which can be readily stripped. The results showed a maximum Fe stripping efficiency of 95.5% under optimal condition. Moreover, the extraction capacity of the extractant after stripping was comparable to that of fresh extractant, and decreased only by 2% after 6 cycles, indicating the robustness of this approach for Fe stripping and extractant regeneration.

Keywords: earth elements; red mud; elements recovery; rare earth; recovery red; aliquat 336

Journal Title: Separation Science and Technology
Year Published: 2020

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