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Preparation and curing behavior of microencapsulated curing agents for cold mix epoxy asphalt.

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ABSTRACT:This study aimed to improve control over the curing behavior of cold mix epoxy asphalt by using a microencapsulated curing agent (2-PZ@PC). Prepared through solvent evaporation, the 2-PZ@PC microcapsules had… Click to show full abstract

ABSTRACT:This study aimed to improve control over the curing behavior of cold mix epoxy asphalt by using a microencapsulated curing agent (2-PZ@PC). Prepared through solvent evaporation, the 2-PZ@PC microcapsules had 2-phenylimidazole as the core material and polycarbonate as the shell material. The research examined the impact of core-shell mass ratio on microcapsule morphology and composition. Various equations, including the kinetics equation, Kisinger equation, Flynn-Wall-Ozawa, and Crane equations, were employed to assess the sustained release effect of 2-PZ@PC microcapsules on epoxy resin curing behavior. Fluorescence microscopy and viscosity experiments were used to observe the release state of microcapsules and confirm the retardation phenomenon during construction. Optimal 2-PZ@PC microcapsules displayed a smooth spherical morphology and a maximum encapsulation rate of 32 wt% at a 1:1 core-shell ratio. The microencapsulated curing agent effectively regulated cold mix epoxy asphalt's curing behavior, enhancing retention time control and application reliability.

Keywords: microencapsulated curing; cold mix; mix epoxy; epoxy asphalt; curing behavior

Journal Title: Journal of microencapsulation
Year Published: 2023

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