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Optimisation of the CZTSe thin film composition obtained by a sequential electrodeposition process

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ABSTRACT The influence of the elemental composition of CuZnSn coatings deposited by electrodeposition on the formation of the Cu2ZnSnSe4 crystal structure following a selenisation process was investigated using X-ray diffraction,… Click to show full abstract

ABSTRACT The influence of the elemental composition of CuZnSn coatings deposited by electrodeposition on the formation of the Cu2ZnSnSe4 crystal structure following a selenisation process was investigated using X-ray diffraction, scanning electron microscopy and Raman spectroscopy. This study showed that the optimum alloy ratio to achieve the Cu2ZnSnSe4 crystal without impurity phases was in the range of 0.37–0.50 for Cu/(Zn+Sn) and 2.5–4 for Zn/Sn.

Keywords: thin film; electrodeposition; process; cztse thin; composition; optimisation cztse

Journal Title: Surface Engineering
Year Published: 2019

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