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Conoscopic image of a biaxial negative in a reentrant discotic – biaxial nematic phase transition

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ABSTRACT Conoscopic images have confirmed the occurrence of biaxial positive ( and biaxial negative ( ) nematic phases between the two uniaxial nematic (discotic – and calamitic – ) phases.… Click to show full abstract

ABSTRACT Conoscopic images have confirmed the occurrence of biaxial positive ( and biaxial negative ( ) nematic phases between the two uniaxial nematic (discotic – and calamitic – ) phases. Biaxial positive ( ) nematic phase was also optically characterised between two uniaxial phases. These nematic phases are found in different phase diagram lines of potassium laurate ( ), decanol ( ) and deuterium oxide ( ) lyotropic mixtures. In limited concentration range between the two phase diagram lines the following phase sequence ( ) is determined here through conoscopic images. An analysis of the meaning of this result leads us to conclude that the biaxial nematic phase range between uniaxial nematic phases of phase diagrams with nematic lyotropic materials is separated in two regions: one has an optically positive signal and the other, having an optical negative signal. Graphical abstract

Keywords: phase; conoscopic image; biaxial nematic; nematic phase; nematic phases; biaxial negative

Journal Title: Liquid Crystals
Year Published: 2020

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