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Effect of aluminum nanoparticles on rheological behavior of HTPB-based composite rocket propellant

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ABSTRACT The aim of this article was to understand the rheology of composite propellant containing aluminum nanoparticles, as it is a highly filled mixture of solids and is difficult to… Click to show full abstract

ABSTRACT The aim of this article was to understand the rheology of composite propellant containing aluminum nanoparticles, as it is a highly filled mixture of solids and is difficult to process. Aluminum nanoparticles utilized as a filler were characterized using X-ray diffraction spectroscopy, scanning and transmission electron microscopy. It was confirmed that the material was pure aluminum, spherical in shape and nano-sized (96.8 nm). The effects of shear stress, shear rate, strain, aluminum nanoparticles concentration, and shear time on rheology were investigated thoroughly, which confirmed a non-Newtonian, time-dependent, shear-thinning, and viscoplastic flow behavior. The composition which had 0% nanoparticles showed the lowest thixotropy index of 50.86 Pa/s, and the difference was almost minimal for compositions containing 0% and 6% nanoparticles. The propellant containing 6% nanoparticles did not yield, as compared to the compositions. The results indicate that nanoparticles have a considerable effect on the rheology of the composite propellant. Graphical Abstract

Keywords: aluminum nanoparticles; rheology; effect aluminum; aluminum; behavior

Journal Title: Journal of Energetic Materials
Year Published: 2018

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