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Investigations on electrical and optical properties of samarium chloride coordinated urea-thiourea semi-organic complex

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ABSTRACT Samarium chloride coordinated urea-thiourea semi-organic complex was prepared at room temperature by slow evaporation technique. The complexes were prepared with high degree of crystallinity. The unit cell parameters determined… Click to show full abstract

ABSTRACT Samarium chloride coordinated urea-thiourea semi-organic complex was prepared at room temperature by slow evaporation technique. The complexes were prepared with high degree of crystallinity. The unit cell parameters determined by powder X-ray diffraction reveals the complex to be having orthorhombic system with Pnma space group. The dielectric measurements were made by impedance spectroscopy and various dielectric parameters were studied as a function of temperature and frequency. The ac conductivity is governed by Arrhenius type behaviour and universal power law. In optical analysis, the transmittance characteristics of complexes were studied in ultra-violet and visible region of electromagnetic spectrum.

Keywords: samarium chloride; semi organic; chloride coordinated; thiourea semi; coordinated urea; urea thiourea

Journal Title: Integrated Ferroelectrics
Year Published: 2017

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