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Grain size dependent thermal and electrical behaviour of La0.6Sr0.4Co0.2Fe0.8O3-δ

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ABSTRACT La0.6Sr0.4Co0.2Fe0.8O3-δ has been synthesized by an advanced combustion technique with step wise modifications by various combustion additives. The quantitative values of the grain sizes obtained from a programmed software… Click to show full abstract

ABSTRACT La0.6Sr0.4Co0.2Fe0.8O3-δ has been synthesized by an advanced combustion technique with step wise modifications by various combustion additives. The quantitative values of the grain sizes obtained from a programmed software has been compared and confirmed by the SEM images. From the grain growth kinetics it was confirmed that sintering mechanism was initiated by volume diffusion. The thermal expansion behaviour and electrical DC conductivity studied as function of temperature have significant dependence on the grain size and the grain size distribution. The conductivity has been observed to be due to electronic contributions only and has been co related to the defect reactions.

Keywords: 4co0 2fe0; 6sr0 4co0; size; 2fe0 8o3; grain size; la0 6sr0

Journal Title: Integrated Ferroelectrics
Year Published: 2017

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