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Novel calix[4]arene based metallo-supramolecular complex for recognition of cyanide ions in aqueous medium

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Abstract A novel bis-naphthalimidocalix[4]arene-Cu(II) supramolecular complex has been observed to provide an efficient recognition system for CN− ions in aqueous medium. The binding stoichiometry of bis-naphthalimidocalix[4]arene and copper ion has… Click to show full abstract

Abstract A novel bis-naphthalimidocalix[4]arene-Cu(II) supramolecular complex has been observed to provide an efficient recognition system for CN− ions in aqueous medium. The binding stoichiometry of bis-naphthalimidocalix[4]arene and copper ion has been found to be 1:1 while that for bis-naphthalimidocalix[4]arene-Cu(II) and cyanide ion it has been determined to be 1:2.

Keywords: supramolecular complex; recognition; arene; ions aqueous; aqueous medium

Journal Title: Supramolecular Chemistry
Year Published: 2017

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