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A pair of humulane sesquiterpenoid enantiomers from Syringa pinnatifolia

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Abstract Two humulane-type sesquiterpenoids, namely (+)-alashanoid I (1a) and (–)-alashanoid I (1b), were isolated as a pair of enantiomers from the peeled stems of Syringa pinnatifolia. Their structures were elucidated… Click to show full abstract

Abstract Two humulane-type sesquiterpenoids, namely (+)-alashanoid I (1a) and (–)-alashanoid I (1b), were isolated as a pair of enantiomers from the peeled stems of Syringa pinnatifolia. Their structures were elucidated by extensive spectroscopic data (1 D and 2 D NMR, UV, and IR), and the absolute configurations were resolved by X-ray diffraction and experimental and calculated ECD data analysis. Graphical Abstract

Keywords: syringa pinnatifolia; pair humulane; humulane; sesquiterpenoid enantiomers; humulane sesquiterpenoid

Journal Title: Natural Product Research
Year Published: 2018

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