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Azines from one-pot reaction of thiosemicarbazones

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ABSTRACT Thermolysis and/or microwave irradiation of thiosemicarbazones gave the corresponding isothiocyanates, which on addition of either activated nitriles or aldehydes furnished various types of azines. The mechanism was discussed. The… Click to show full abstract

ABSTRACT Thermolysis and/or microwave irradiation of thiosemicarbazones gave the corresponding isothiocyanates, which on addition of either activated nitriles or aldehydes furnished various types of azines. The mechanism was discussed. The structures of products were proved by MS, IR, NMR, and elemental analyses. GRAPHICAL ABSTRACT

Keywords: pot reaction; reaction thiosemicarbazones; chemistry; azines one; one pot

Journal Title: Journal of Sulfur Chemistry
Year Published: 2017

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